Semi-conductive helical homochiral metal–organic frameworks based on enantiomeric proline derivatives
Author:
Affiliation:
1. School of Chemistry and Chemical Engineering
2. Zunyi Normal College
3. Zunyi
4. P. R. China
5. School of Pharmaceutical Sciences and Yunnan Key Laboratory of Pharmacology for Natural Products
Abstract
Chiral ligands (S)-H2PCA and (R)-H2PCA were synthesized by attaching (S)- and (R)-proline to 1,4-dicarboxybenzene. They further reacted with Cu(ii) and Co(ii) ions to obtain two pairs of helical homochiral MOFs with photocatalytic behaviours.
Funder
Natural Science Foundation of Guizhou Province
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/CE/D0CE00262C
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