Affiliation:
1. School of Chemistry, Cardiff University, Park Place, Cardiff CF10 3AT, UK
Abstract
Compared with the (2p)C/(2p)O orbital interactions, the smaller (2p)C/(3p)S overlap in thionated molecules results in a weaker antibonding character in the LUMO, and hence the superior electron affinity, despite the lower electronegativity of sulfur.
Funder
Engineering and Physical Sciences Research Council
Cardiff University
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Cited by
2 articles.
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