Enantiocontrol by assembled attractive interactions in copper-catalyzed asymmetric direct alkynylation of α-ketoesters with terminal alkynes: OH⋯O/sp3-CH⋯O two-point hydrogen bonding combined with dispersive attractions-Reference-Cited by-同舟云学术

Enantiocontrol by assembled attractive interactions in copper-catalyzed asymmetric direct alkynylation of α-ketoesters with terminal alkynes: OH⋯O/sp3-CH⋯O two-point hydrogen bonding combined with dispersive attractions

Published:2018 Issue:14 Volume:9 Page:3484-3493
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Schwarzer Martin C.¹²³⁴^ORCID,Fujioka Akane⁵⁶⁷⁸⁴,Ishii Takaoki⁵⁶⁷⁸⁴,Ohmiya Hirohisa⁹¹⁰¹¹¹²⁴^ORCID,Mori Seiji¹²³⁴^ORCID,Sawamura Masaya⁵⁶⁷⁸⁴^ORCID

Affiliation:

1. Institute of Quantum Beam Science

2. Ibaraki University

3. Mito

4. Japan

5. Department of Chemistry

6. Faculty of Science

7. Hokkaido University

8. Sapporo 060-0810

9. Division of Pharmaceutical Sciences

10. Graduate School of Medical Sciences

11. Kanazawa University

12. Kanazawa 920-1192

Abstract

A chiral copper catalyst selects enantiofaces by assembled attractive interactions.

Funder

Japan Science and Technology Agency

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/SC/C8SC00527C

Reference61 articles.

1. Catalytic asymmetric synthesis by means of secondary interaction between chiral ligands and substrates

2. Power of Cooperativity: Lewis Acid-Lewis Base Bifunctional Asymmetric Catalysis

3. CH/π Attraction: The Origin of Enantioselectivity in Transfer Hydrogenation of Aromatic Carbonyl Compounds Catalyzed by Chiralη6-Arene-Ruthenium(II) Complexes

4. Cooperative Catalysis of Metal and OH⋅⋅⋅O/sp3-CH⋅⋅⋅O Two-Point Hydrogen Bonds in Alcoholic Solvents: Cu-Catalyzed Enantioselective Direct Alkynylation of Aldehydes with Terminal Alkynes

5. Enantioselective Addition of Terminal Alkynes to Aldehydes Catalyzed by a Cu(I)−TRAP Complex

Cited by 42 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Advances and Prospects in Understanding London Dispersion Interactions in Molecular Chemistry;Angewandte Chemie International Edition;2024-01-04

2. Advances and Prospects in Understanding London Dispersion Interactions in Molecular Chemistry;Angewandte Chemie;2024-01-04

3. Well-defined Cu(i) complexes based on [N,P]-pyrrole ligands catalyzed a highly endoselective 1,3-dipolar cycloaddition;Dalton Transactions;2024

4. Pd((R)-DTBM-SEGphos)Cl₂-catalyzed kinetic resolution of tertiary propargylic alcohols;Organic Chemistry Frontiers;2024

5. Computational molecular refinement to enhance enantioselectivity by reinforcing hydrogen bonding interactions in major reaction pathway;Chemical Science;2023