Light-driven redox deracemization of indolines and tetrahydroquinolines using a photocatalyst coupled with chiral phosphoric acid-Reference-Cited by-同舟云学术

Light-driven redox deracemization of indolines and tetrahydroquinolines using a photocatalyst coupled with chiral phosphoric acid

Published:2023 Issue:7 Volume:14 Page:1715-1723
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Chen Qipeng¹,Zhu Yuanli¹,Shi Xujing¹,Huang Renfu¹,Jiang Chuang¹,Zhang Kun¹,Liu Guohua¹^ORCID

Affiliation:

1. International Joint Laboratory on Resource Chemistry of Ministry of Education, Shanghai Key Laboratory of Rare Earth Functional Materials, Shanghai Normal University, Shanghai 200234, P. R. China

Abstract

A light-driven redox deracemization to prepare optically pure cyclamines from their racemates is developed. This reaction provides a wide range of chiral indolines and tetrahydroquinolines with high yields and enantioselectivities.

Funder

National Natural Science Foundation of China

Shanghai Science and Technology Development Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D2SC06340A

Reference97 articles.

1. Recent developments in enantioselective photocatalysis

2. Catalytic enantioselective reactions driven by photoinduced electron transfer