The reactivity of 1,1-dichloro-2,2-di-tert-butyldiphosphane towards lithiated metal carbonyls: a new entry to phosphanylphosphinidene dimers-Reference-Cited by-同舟云学术

The reactivity of 1,1-dichloro-2,2-di-tert-butyldiphosphane towards lithiated metal carbonyls: a new entry to phosphanylphosphinidene dimers

Published:2016 Issue:12 Volume:45 Page:4961-4964
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Grubba Rafał¹²³⁴⁵,Zauliczny Mateusz¹²³⁴⁵,Ponikiewski Łukasz¹²³⁴⁵,Pikies Jerzy¹²³⁴⁵

Affiliation:

1. Chemical Faculty

2. Department of Inorganic Chemistry

3. Gdansk University of Technology

4. Pl-80-233 Gdansk

5. Poland

Abstract

Reactions of [Cp*(OC)₃M]Li (Cp* = C₅Me₅, M = Mo, W) towards t-Bu₂P–PCl₂ lead to the formation of phosphanylphosphinidene dimers [Cp*(OC)₃M(η²-t-Bu₂P–P)]₂ in fairly good yields.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT04983K

Reference35 articles.

1. A Novel Entry to the PC-Double Bond: the“Phospha-Wittig” Reaction

2. Nucleophilic or Electrophilic Phosphinidene Complexes MLnPH; What Makes the Difference?

3. The Development of a Carbene-like Chemistry with Terminal Phosphinidene Complexes

4. Electrophilic Terminal-Phosphinidene Complexes: Versatile Phosphorus Analogues of Singlet Carbenes

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