Single crystal structures and theoretical calculations of uranium endohedral metallofullerenes (U@C2n, 2n = 74, 82) show cage isomer dependent oxidation states for U

Author:

Cai Wenting1234,Morales-Martínez Roser5678,Zhang Xingxing910111213,Najera Daniel1234,Romero Elkin L.1234,Metta-Magaña Alejandro1234,Rodríguez-Fortea Antonio5678ORCID,Fortier Skye1234ORCID,Chen Ning910111213ORCID,Poblet Josep M.5678ORCID,Echegoyen Luis1234ORCID

Affiliation:

1. Department of Chemistry

2. University of Texas at El Paso

3. El Paso

4. USA

5. Departament de Química Física i Inorgànica

6. Universitat Rovira i Virgili

7. 43007 Tarragona

8. Spain

9. Laboratory of Advanced Optoelectronic Materials

10. College of Chemistry

11. Chemical Engineering and Materials Science

12. Soochow University

13. Suzhou

Abstract

First X-ray structures and metal oxidation state dependence on cage isomerism for U-EMFs.

Funder

National Science Foundation

Welch Foundation

Spanish Ministry of Science

Generalitat de Catalunya

Institució Catalana de Recerca i Estudis Avançats

Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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