Enhancement of the intrinsic fluorescence of acridine and its induced circularly polarized luminescence (CPL) in ionic two-coordinate coinage metal complexes

Author:

Li Ke-Die1,Zheng Shu-Jia1,Song Shi-Quan2,Yu Si-Qi1,Feng Yue-Yang1,Liu Junzi1,Zheng You-Xuan2ORCID,Li Tian-Yi1ORCID

Affiliation:

1. Department of Chemistry, University of Science and Technology Beijing, Beijing, 100083, P. R. China

2. School of Chemistry and Chemical Engineering, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210023, P. R. China

Abstract

Enhanced blue fluorescence of acridine is achieved in carbene–M–acridine ionic complexes, where M is Cu(i) and Ag(i), approaching 50%. With the help of chiral counter ions, circularly polarized fluorescence of acridine is induced in crystalline state.

Funder

National Natural Science Foundation of China

Beijing Municipal Natural Science Foundation

Publisher

Royal Society of Chemistry (RSC)

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