Copper-catalyzed synthesis of primary amides through reductive N–O cleavage of dioxazolones-Reference-Cited by-同舟云学术

Copper-catalyzed synthesis of primary amides through reductive N–O cleavage of dioxazolones

Published:2024 Issue:14 Volume:14 Page:9440-9444
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Bae Hyeonwoong¹²,Park Jinhwan¹²,Yoon Rahyun²,Lee Seunghoon¹²^ORCID,Son Jongwoo¹²^ORCID

Affiliation:

1. Department of Chemical Engineering (BK21 FOUR Graduate Program), Dong-A University, 37 Nakdong-Daero 550beon-gil, Saha-gu, Busan 49315, South Korea

2. Department of Chemistry, Dong-A University, 37 Nakdong-Daero 550beon-gil, Saha-gu, Busan 49315, South Korea

Abstract

Reaction of dioxazolones in the presence of a copper catalyst and a silane is represented. Mild reductive reaction conditions for the N–O bond cleavage and large-scale protocols are also highlighted with excellent tolerance in the presence of water.

Funder

National Research Foundation of Korea

Ministry of Environment

Korea Environmental Industry and Technology Institute

Ministry of Science and ICT, South Korea

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/RA/D4RA00320A

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