Dual tuning of the de-/hydrogenation thermodynamics and kinetics of the Mg–Ni alloy by introducing the Ag–H bond: enhanced hydrogen storage properties at moderate temperatures

Author:

Cao Wenchao12,Ding Xin12,Chen Ruirun12ORCID,Zhang Jiaxin12,Zhang Yong2,Guo Jingjie12,Fu Hengzhi12

Affiliation:

1. National Key Laboratory for Precision Hot Processing of Metals, Harbin Institute of Technology, No. 92, West Dazhi Street, Harbin, Heilongjiang, 150001, China

2. School of Materials Science and Engineering, Harbin Institute of Technology, Harbin, 150000, China

Abstract

The onset dehydrogenation temperature of Mg85Ni14.8Ag0.2 reduces to 178 °C due to the enhanced hydrogen pumping effect of Mg2NiH4 by adjusting the Ni–H bond.

Funder

National Natural Science Foundation of China

China Postdoctoral Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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