Hydrogen bond dynamics of superheated water and methanol by ultrafast IR-pump and EUV-photoelectron probe spectroscopy

Author:

Vöhringer-Martinez E.1234,Link O.567,Lugovoy E.89101112,Siefermann K. R.89,Wiederschein F.1314,Grubmüller H.1314,Abel B.89101112

Affiliation:

1. Departamento de Físico-Química

2. Facultad de Ciencias Químicas

3. Universidad de Concepción

4. Concepción, Chile

5. Institut für Physikalische Chemie

6. Georg August Universität Göttingen

7. Göttingen, Germany

8. Leibniz-Institute of Surface Modification (IOM)

9. 04318 Leipzig, Germany

10. Wilhelm-Ostwald-Institut für Physikalische und Theoretische Chemie

11. Universität Leipzig

12. 04103 Leipzig, Germany

13. Max-Planck-Institut für biophysikalische Chemie

14. 37077 Göttingen, Germany

Abstract

Snapshot of superheated water 40 ps after fs-IR laser excitation; representative aggregates formed during the simulation (close-up) compared to one obtained from superheated methanol phase (inset).

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference79 articles.

1. M. R. Manaa , Chemistry at Extreme Conditions , Elsevier Science , New York , 2005

2. Roles of Water for Chemical Reactions in High-Temperature Water

3. Organic Chemical Reactions in Supercritical Water

4. Relationship between structural order and the anomalies of liquid water

5. P. G. Debenedetti , Metastable Liquids: Concepts and Principles , Princeton Academic Press , Princeton, New Jersey , 1996

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