Reversible hetero-Diels–Alder amine hardener as drop-in replacement for healable epoxy coatings-Reference-Cited by-同舟云学术

Reversible hetero-Diels–Alder amine hardener as drop-in replacement for healable epoxy coatings

Published:2022 Issue:6 Volume:13 Page:741-747
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Rajappan Sinu C.¹,Davis Brad J.¹,Dishner Isaiah T.¹^ORCID,Thornell Travis L.²,Peyrefitte John J.¹,Simon Yoan C.¹^ORCID

Affiliation:

1. School of Polymer Science and Engineering, The University of Southern Mississippi, 118 College Dr. #5050, Hattiesburg, MS 39406, USA

2. Environmental Laboratory, U.S. Army Engineer Research and Development Center, 3909 Halls Ferry Road, Vicksburg, MS 39180, USA

Abstract

Replacing commercial hardeners with bio-sourced fatty acids linked by hetero Diels–Alder (HDA) motifs enabled epoxy-amine coatings with intrinsic self-healing properties. The HDA-based coatings demonstrate scratch healing at 95 °C within 15 min.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2022/PY/D1PY00917F

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