Sumanene-functionalised bis(terpyridine)–ruthenium(ii) complexes showing photoinduced structural change and cation sensing

Author:

Han Junyi1,Yakiyama Yumi12ORCID,Takeda Youhei1ORCID,Sakurai Hidehiro12ORCID

Affiliation:

1. Division of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan

2. Innovative Catalysis Science Division, Institute for Open and Transdisciplinary Research Initiatives (ICS-OTRI), Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan

Abstract

Ru(ii) complexes with sumanene-functionalised terpyridine ligands exhibited dual emission via the TICT mechanism due to the relatively easy rotation around the sumanene–terpyridine bond axis. They also showed selective Li+ sensing ability.

Funder

Japan Society for the Promotion of Science

Otsuka Toshimi Scholarship Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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