NHC-catalyzed radical acylation of cycloalkyl silyl peroxides to access 1,6-,1,7-, and 1,8-diketones-Reference-Cited by-同舟云学术

NHC-catalyzed radical acylation of cycloalkyl silyl peroxides to access 1,6-,1,7-, and 1,8-diketones

Published:2023 Issue:88 Volume:59 Page:13175-13178
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Liu Chaolei¹,Wang Jingyi¹,Liu Xinlong¹,Feng Jie¹^ORCID,Du Ding¹^ORCID

Affiliation:

1. State Key Laboratory of Natural Medicines, School of Science, China Pharmaceutical University, Nanjing 210009, P. R. China

Abstract

An NHC organocatalytic radical acylation of cycloalkyl silyl peroxides with aldehydes was developed for the efficient and rapid synthesis of long-chain 1,6-/1,7-/1,8-diketones, especially unsymmetrical ones.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC04765B

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