The influence of acceptor nucleophilicity on the glycosylation reaction mechanism
Author:
Affiliation:
1. Leiden Institute of Chemistry
2. Leiden University
3. 2333 CC Leiden
4. The Netherlands
Abstract
The acceptor dependence on the glycosylation stereoselectivity is revealed by a systematic study employing model acceptors of gradually changing nucleophilicity.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/SC/C6SC04638J
Reference78 articles.
1. Opportunities and challenges in synthetic oligosaccharide and glycoconjugate research
2. M. Sinnott , Carbohydrate Chemistry and Biochemistry: Structure and Mechanism, The Royal Society of Chemistry, 2007
3. A. V. Demchenko , Handbook of Chemical Glycosylation: Advances in Stereoselectivity and Therapeutic Relevance, Wiley-VCH Verlag GmbH & Co. KGaA, 2008
4. C. S. Bennett , Selective Glycosylations: Synthetic Methods and Catalysts, Wiley VCH Verlag GmbH, 2017
5. One-Pot Synthesis of Tetra- and Pentasaccharides from Monomeric Building Blocks Using the Principles of Orthogonality and Reactivity Tuning
Cited by 130 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献
1. Synthesis of sialyl halides with various acyl protective groups;Carbohydrate Research;2024-02
2. Alternative Routes to 4,6‐O‐Benzylidene β‐Thioglycosides;Helvetica Chimica Acta;2024-01-31
3. Exploring the Dual Functions of Distal Acyl Group Direction in Various Nucleophilic Environments;The Journal of Organic Chemistry;2024-01-30
4. Anomeric Triflates versus Dioxanium Ions: Different Product-Forming Intermediates from 3-Acyl Benzylidene Mannosyl and Glucosyl Donors;The Journal of Organic Chemistry;2024-01-18
5. Acetal Substitution Reactions: Stereoelectronic Effects, Conformational Analysis, Reactivity vs Selectivity, and Neighboring-Group Participation;Synlett;2024-01-16
1.学者识别学者识别
2.学术分析学术分析
3.人才评估人才评估
"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370
www.globalauthorid.com
TOP
Copyright © 2019-2024 北京同舟云网络信息技术有限公司 京公网安备11010802033243号 京ICP备18003416号-3