Different manifestations of enhanced π-acceptor ligation at every redox level of [Os(9-OP)L2]n, n = 2+, +, 0, − (9-OP− = 9-oxidophenalenone and L = bpy or pap)-Reference-Cited by-同舟云学术

Different manifestations of enhanced π-acceptor ligation at every redox level of [Os(9-OP)L2]n, n = 2+, +, 0, − (9-OP− = 9-oxidophenalenone and L = bpy or pap)

Published:2016 Issue:45 Volume:45 Page:18241-18251
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Hazari Arijit Singha¹²³⁴,Paretzki Alexa⁵⁶⁷⁸,Fiedler Jan⁹¹⁰¹¹¹²¹³,Zalis Stanislav⁹¹⁰¹¹¹²¹³,Kaim Wolfgang⁵⁶⁷⁸,Lahiri Goutam Kumar¹²³⁴

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology Bombay

3. Mumbai 400076

4. India

5. Institut für Anorganische Chemie

6. Universität Stuttgart

7. D-70550 Stuttgart

8. Germany

9. J. Heyrovský Institute of Physical Chemistry

10. v.v.i.

11. Academy of Sciences of the Czech Republic

12. CZ-18223 Prague

13. Czech Republic

Abstract

Enhanced metal–ligand and ligand–ligand interactions are promoted in an osmium complex with non-innocent donor and acceptor ligands.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT03764J

Reference64 articles.

1. Resonating Valence Bond Ground State in Oxygen-Functionalized Phenalenyl-Based Neutral Radical Molecular Conductors

2. Synthesis and characterization of germanium (IV) and silicon (IV) complexes derived from 9-hydroxyphenalenone: X-ray crystal and molecular structure of tris-(9-oxophenalenone)-germanium (IV) and silicon (IV) salts

3. Phenalenyl-Based Molecules: Tuning the Lowest Unoccupied Molecular Orbital to Design a Catalyst

4. Experimental and DFT Evidence for the Fractional Non-Innocence of a β-Diketonate Ligand

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