Co-ligand tuned pyrimidine-2-carboxylate Mn(ii) complexes from a 2D 63 layer to an interpenetrated srs-net-Reference-Cited by-同舟云学术

Co-ligand tuned pyrimidine-2-carboxylate Mn(ii) complexes from a 2D 63 layer to an interpenetrated srs-net

Published:2017 Issue:26 Volume:46 Page:8593-8597
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Sun Rui¹²³⁴,Gao Su-Mei⁵⁶⁷⁸,Wang Shao-Qiang¹²³⁴,Song Wei-Chao⁹¹⁰¹¹¹²⁸,Zhao Jiong-Peng¹²³⁴^ORCID,Liu Fu-Chen¹²³⁴^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering

2. Tianjin University of Technology

3. Tianjin 300384

4. China

5. School of Electronic and Information Engineering

6. Tianjin Vocational Institute

7. Tianjin 300410

8. P. R. China

9. TKL of Structure and Performance for Functional Molecules

10. College of Chemistry

11. Tianjin Normal University

12. Tianjin 300387

Abstract

Formate tuned chloride pyrimidine-2-carboxylate Mn(ii) complexes from a 2D 6³ layer to a polar 3D interpenetrated srs-net exhibit an obvious SHG response of approximately 0.8 × KH₂PO₄ (KDP). Furthermore, 2 is an antiferromagnet with a field induced spin flop transition.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Tianjin

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT01045A

Reference46 articles.

1. One-dimensional coordination polymer [Co(H2O)4(pyz)](NO3)2·2H2O (pyz=pyrazine) with intra- and inter-chain H-bonds: structure, electronic spectral studies and magnetic properties

2. Substitution reactions in metal–organic frameworks and metal–organic polyhedra