Access to pyrrolines and fused diaziridines by selective radical addition to homoallylic diazirines

Author:

Ma Zhigang1,Wu Xinxin1ORCID,Li Haotian1,Cao Zhu2,Zhu Chen12ORCID

Affiliation:

1. Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, 199 Ren-Ai Road, Suzhou, Jiangsu 215123, China

2. Frontiers Science Center for Transformative Molecules, Shanghai Key Laboratory for Molecular Engineering of Chiral Drugs, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240, China

Abstract

A novel, divergent radical cyclization of homoallylic diazirines for the synthesis of pyrrolines and fused diaziridines is described.

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Natural Science Foundation of Jiangsu Province

Priority Academic Program Development of Jiangsu Higher Education Institutions

Program of Shanghai Academic Research Leader

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference57 articles.

1. J. W.Daly , H. M.Garraffo and T. F.Spande , in Alkaloids Chem. Biol. Perspect. , ed. S. W. Pelletier , Elsevier , Oxford , 1999 , pp. 1–161

2. T.Aniszewski , in Alkaloids – Secrets Life , Elsevier , 2007 , pp. 61–139

3. The Venom Alkaloids from Some African Monomorium Species

4. Venom Alkaloid Chemistry of Australian Species of theMonomorium rothsteiniComplex, with Particular Reference to Taxonomic Implications

5. Update on the defensive chemicals of the little black ant, Monomorium minimum (Hymenoptera: Formicidae)

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