A new access to diazaphospholes <i>via</i> cycloaddition–cycloreversion reactions on triazaphospholes-Reference-Cited by-同舟云学术

A new access to diazaphospholes via cycloaddition–cycloreversion reactions on triazaphospholes

Published:2022 Issue:56 Volume:58 Page:7745-7748
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Dettling Lea¹^ORCID,Papke Martin¹,Sklorz Julian A. W.¹,Buzsáki Dániel²^ORCID,Kelemen Zsolt²,Weber Manuela¹,Nyulászi László²^ORCID,Müller Christian¹^ORCID

Affiliation:

1. Freie Universität Berlin, Institute of Chemistry and Biochemistry, Fabeckstr. 34/36, 14195, Berlin, Germany

2. Department of Inorganic and Analytical Chemistry, Budapest University of Technology and MTA-BME Computation Driven Chemistry Research Group, Műegyetem rkp. 3, H-1111, Budapest, Hungary

Abstract

The [4+2] cycloaddition of a triazaphosphole with hexafluoro-2-butyne, followed by a cycloreversion reaction under elimination of pivaloyl nitrile, affords selectively a novel bis-CF3-substituted diazaphosphole in high yield.

Funder

Hungarian Academy of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC02269A

Reference28 articles.

1. Electronic structure and aromaticity of azaphospholes

2. [3+2]-Cycloaddition Reactions of a Stable Phosphaalkyne—Transition from Singly to Doubly Coordinated Phosphorus

3. Aromaticity of Phosphorus Heterocycles

4. The facile assembly of bis-, tris- and poly(triazaphosphole) systems using “click” chemistry

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