Potassium <i>tert</i>-butoxide promoted regioselective deuteration of pyridines-Reference-Cited by-同舟云学术

Potassium tert-butoxide promoted regioselective deuteration of pyridines

Published:2022 Issue:21 Volume:58 Page:3497-3500
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Li Yan¹²,Zheng Chenxu¹²,Jiang Zhi-Jiang¹^ORCID,Tang Jianbo¹³,Tang Bencan⁴^ORCID,Gao Zhanghua¹^ORCID

Affiliation:

1. School of Biological and Chemical Engineering, NingboTech University, Ningbo, 315100, People's Republic of China

2. College of Chemical and Biological Engineering, Zhejiang University, Hangzhou, 310012, People's Republic of China

3. College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, 730000, People's Republic of China

4. Department of Chemical and Environment Engineering, The University of Nottingham Ningbo China, Ningbo, 315100, People's Republic of China

Abstract

Regioselective β- and γ-deuteration of pyridine was achieved under mild condition through a carbanion pathway with dimsyl-d5 intermediate.

Funder

Natural Science Foundation of Ningbo

Ningbo Municipal Bureau of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D1CC07128A

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