An efficient method for the preparation of tert-butyl esters from benzyl cyanide and tert-butyl hydroperoxide under the metal free condition
Author:
Affiliation:
1. Non-Power Nuclear Technology Collaborative Innovation Center
2. School of Nuclear Technology and Chemistry & Life Science
3. Hubei University of Science and Technology
4. Xianning 437100
5. China
Abstract
A novel protocol to synthesize tert-butyl esters from benzyl cyanides and tert-butyl hydroperoxide has been successfully achieved. Csp3–H bond oxidation, C–CN bond cleavage and C–O bond formation proceeded smoothly in one pot under the metal-free condition.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA20966A
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