An efficient method for the preparation of tert-butyl esters from benzyl cyanide and tert-butyl hydroperoxide under the metal free condition

Author:

Chen Xiuling12345,Li Yan12345,Wu Minghu12345,Guo Haibing12345,Jiang Longqiang12345,Wang Jian12345,Sun Shaofa12345

Affiliation:

1. Non-Power Nuclear Technology Collaborative Innovation Center

2. School of Nuclear Technology and Chemistry & Life Science

3. Hubei University of Science and Technology

4. Xianning 437100

5. China

Abstract

A novel protocol to synthesize tert-butyl esters from benzyl cyanides and tert-butyl hydroperoxide has been successfully achieved. Csp3–H bond oxidation, C–CN bond cleavage and C–O bond formation proceeded smoothly in one pot under the metal-free condition.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference68 articles.

1. A Mild Protocol for the Conversion of Simple Esters to tert-Butyl Esters

2. J. Otera , Eserification Methods, in Reactions and applications, Wiley VCH, Verlag Gmbh and KGaA, Weinheim, Germany, 2003

3. R. C. Larock , Comprehensive Organic transformations, VCH, New York, 1989, p. 966

4. The Reversible Dissociation of t-Butyl Esters. Structural Effects and Reactions Mechanism

5. In Situ Synthesis, Characterization of SiPMo‐X, and Different Catalytic Properties of SiPMo‐X and SiPW‐X

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