Copolymers from norbornene and norbornadiene with organized morphologies and high Tg values obtained via ROMP with a highly reactive [RuCl3(PCy3)2] complex-Reference-Cited by-同舟云学术

Copolymers from norbornene and norbornadiene with organized morphologies and high Tg values obtained via ROMP with a highly reactive [RuCl3(PCy3)2] complex

Published:2016 Issue:11 Volume:40 Page:9424-9431
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Ferraz C. P.¹²³⁴⁵,Fonseca L. R.¹²³⁴⁵,Tomazetti V.¹²³⁴⁵,Silva F. C. S.¹²³⁴⁵,Lima-Neto B. S.¹²³⁴⁵,Carvalho V. P.⁶⁷⁸⁹¹⁰

Affiliation:

1. Instituto de Química de São Carlos

2. Universidade de São Paulo

3. CP 780

4. CEP 13560-970

5. São Carlos

6. Faculdade de Ciências e Tecnologia

7. Universidade Estadual Paulista

8. CEP 19060-900

9. Presidente Prudente

10. Brazil

Abstract

[RuCl₃(PCy₃)₂] presented high reactivity toward ROMP of norbornene and norbornadiene in air, in the presence of ethyl diazoacetate, resulting in copolymers with high T_g values and organized morphologies.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/NJ/C6NJ02096H

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5. A novel shape memory polynorbornene functionalized with poly(ɛ-caprolactone) side chain and cyano group through ring-opening metathesis polymerization

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