Enantioconvergent synthesis of chiral fluorenols from racemic secondary alcohols <i>via</i> Pd(<scp>ii</scp>)/chiral norbornene cooperative catalysis-Reference-Cited by-同舟云学术

Enantioconvergent synthesis of chiral fluorenols from racemic secondary alcohols via Pd(ii)/chiral norbornene cooperative catalysis

Published:2024 Issue:21 Volume:15 Page:7975-7981
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Ding Bo¹,Xue Qilin¹,Wei Han²,Chen Jiangwei¹,Liu Ze-Shui¹,Cheng Hong-Gang¹^ORCID,Cong Hengjiang¹^ORCID,Tang Jianting³,Zhou Qianghui¹²^ORCID

Affiliation:

1. Engineering Research Center of Organosilicon Compounds & Materials (Ministry of Education), Hubei Key Lab on Organic and Polymeric OptoElectronic Materials, College of Chemistry and Molecular Sciences, TaiKang Center for Life and Medical Sciences, Wuhan University, Wuhan, 430072, China

2. The Institute for Advanced Studies, Wuhan University, Wuhan, 430072, China

3. Key Laboratory of Water Environment Evolution and Pollution Control in Three Gorges Reservoir, School of Environmental and Chemical Engineering, Chongqing Three Gorges University, Chongqing, 404100, China

Abstract

An enantioconvergent strategy for the synthesis of chiral fluorenols from racemic secondary alcohols has been disclosed enabled by Pd(ii)/NBE* cooperative catalysis. The reaction has good functional group compatibility and high enantioselectivity.

Funder

National Key Research and Development Program of China

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC01004C

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