Responsive structural adaptability in ultra-microporous frameworks: guest recognition and macroscopic shape transformations induced by spin transitions within single crystals

Author:

Yang Yu-Ting12,Guo Wei1,Li Yu-Xia3,Liu Zhi-Kun3,Chai Yuqiao2,Li Xing1ORCID,Li Bao4ORCID,Xue Jin-Peng1ORCID

Affiliation:

1. School of Materials Science and Chemical Engineering, Ningbo University, Ningbo, Zhejiang 315211, China

2. School of Material and Chemical Engineering, Ningbo University of Technology, Ningbo, Zhejiang 315211, China

3. Key Laboratory of Cluster Science of Ministry of Education, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 102488, China

4. Key Laboratory of Material Chemistry for Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan, Hubei 430074, China

Abstract

A coordination framework undergoes responsive structural adaptability, associated with spin-crossover activation and CO2/C2H2 separation. Dihydrogen bonds ensure efficient unit functions, enabling a macroscopic shape change in the single crystal.

Funder

Soft Science Foundation of Ningbo

Natural Science Foundation of Ningbo

National Natural Science Foundation of China

Natural Science Foundation of Zhejiang Province

Publisher

Royal Society of Chemistry (RSC)

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