Enantioselective organocatalytic Michael additions of N,N′-dialkylbarbituric acids to enones
Author:
Affiliation:
1. Provincial Key Laboratory of Polyoxometalate Chemistry
2. Provincial Key Laboratory of Natural Medicine and Immuno-Engineering
3. College of Chemistry and Chemical Engineering
4. Henan University
5. Kaifeng
Abstract
N,N′-Dialkylbarbituric acids as cyclic malonamide donors were successfully used in the organocatalytic asymmetric Michael additions with enones, affording the corresponding 5-substituted barbituric acid derivatives with 91–99% ee.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/OB/C7OB02116J
Reference67 articles.
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4. Enantioselective Michael Addition Reactions
5. Recent Advances in Asymmetric Organocatalytic 1,4‐Conjugate Additions
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