Probing the solvation structure and dynamics in ionic liquids by time-resolved infrared spectroscopy of 4-(dimethylamino)benzonitrile

Author:

Ando Rômulo A.12345ORCID,Brown-Xu Samantha E.6789,Nguyen Lisa N. Q.101112513,Gustafson Terry L.101112513ORCID

Affiliation:

1. Laboratório de Espectroscopia Molecular

2. Instituto de Química

3. Departamento de Química Fundamental

4. Universidade de São Paulo

5. São Paulo 05513-970

6. Department of Chemistry

7. Northeastern Illinois University

8. Chicago

9. USA

10. Department of Chemistry and Biochemistry

11. The Ohio State University

12. 2104 Newman & Wolfrom Laboratory

13. Brazil

Abstract

In this work we demonstrate the use of the push–pull model system 4-(dimethylamino)benzonitrile (DMABN) as a convenient molecular probe to investigate the local solvation structure and dynamics by means of time-resolved infrared spectroscopy (TRIR).

Funder

São Paulo Research Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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