Manipulating D–A interaction to achieve stable photoinduced organic radicals in triphenylphosphine crystals-Reference-Cited by-同舟云学术

Manipulating D–A interaction to achieve stable photoinduced organic radicals in triphenylphosphine crystals

Published:2023 Issue:7 Volume:14 Page:1871-1877
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Tang Chunlin¹,Song Lijuan¹,Zhou Kang²,Ren Peng¹^ORCID,Zhao Engui¹^ORCID,He Zikai¹³^ORCID

Affiliation:

1. School of Science, Harbin Institute of Technology, Shenzhen, Guangdong 518055, China

2. Hoffmann Institute of Advanced Materials, Shenzhen Polytechnic, Shenzhen, Guangdong 518055, China

3. School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin, Heilongjiang 150001, China

Abstract

Herein, we realized the quick generation of stable photoinduced radicals in donor–acceptor triarylphosphines with associated color changes of emission and absorption, which was deciphered by the electron paramagnetic resonance (EPR) spectra.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Guangdong Province

Shenzhen Fundamental Research Program

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D2SC05753K

Reference51 articles.

1. Attaching Persistent Organic Free Radicals to Surfaces: How and Why

2. Radicals: Reactive Intermediates with Translational Potential

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