Ring size affects the kinetic and thermodynamic formation of [2]rotaxanes featuring an unsymmetric bis-crown ether component-Reference-Cited by-同舟云学术

Ring size affects the kinetic and thermodynamic formation of [2]rotaxanes featuring an unsymmetric bis-crown ether component

Published:2019 Issue:12 Volume:3 Page:2702-2706
ISSN:2052-1537
Container-title:Materials Chemistry Frontiers
language:en
Short-container-title:Mater. Chem. Front.

Author:

Naito Masaya¹²³⁴⁵^ORCID,Fujino Takaaki¹²³⁴⁵,Tajima Shinya¹²³⁴⁵,Miyagawa Shinobu¹²³⁴⁵,Yoshida Kazuyuki⁶⁷⁸⁹¹⁰,Inoue Hajime⁶⁷⁸⁹¹⁰,Takagawa Hiroaki⁶⁷⁸⁹¹⁰,Kawasaki Tsuneomi¹¹¹²¹³¹⁴¹⁵^ORCID,Tokunaga Yuji¹²³⁴⁵^ORCID

Affiliation:

1. Department of Materials Science and Engineering

2. Faculty of Engineering

3. University of Fukui

4. Bunkyo

5. Fukui 910-8507

6. Forensic Science Laboratory

7. Fukui Prefectural Police H.Q.

8. Ohte

9. Fukui 910-8515

10. Japan

11. Department of Applied Chemistry

12. Tokyo University of Science

13. Kagurazaka

14. Shinjuku-ku

15. Tokyo 162-8601

Abstract

Kinetically and thermodynamically favored [2]rotaxanes, with an axle component positioned within a large and small ring, respectively, were provided by bridging of a [2]pseudorotaxane formed from an unsymmetric mono-crown ether and the ammonium salt.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Materials Science

Link

http://pubs.rsc.org/en/content/articlepdf/2019/QM/C9QM00441F

Reference36 articles.

1. Rotaxanes as ligands: from molecules to materials

2. Transition metal complexes as molecular machine prototypes

3. Rotaxane and Catenane Host Structures for Sensing Charged Guest Species

4. Supramolecular Polymeric Materials via Cyclodextrin–Guest Interactions

5. Rotaxane-Based Molecular Muscles

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