Biocatalytic synthesis of chiral cyclic γ-oxoesters by sequential C–H hydroxylation, alcohol oxidation and alkene reduction-Reference-Cited by-同舟云学术

Biocatalytic synthesis of chiral cyclic γ-oxoesters by sequential C–H hydroxylation, alcohol oxidation and alkene reduction

Published:2017 Issue:21 Volume:19 Page:5122-5130
ISSN:1463-9262
Container-title:Green Chem.
language:en
Short-container-title:Green Chem.

Author:

Brenna Elisabetta¹²³⁴⁵^ORCID,Crotti Michele¹²³⁴⁵,Gatti Francesco G.¹²³⁴⁵^ORCID,Monti Daniela⁶⁵⁷,Parmeggiani Fabio¹²³⁴⁵^ORCID,Pugliese Andrea¹²³⁴⁵,Tentori Francesca¹²³⁴⁵

Affiliation:

1. Politecnico di Milano

2. Dipartimento di Chimica

3. Materiali

4. Ingegneria Chimica

5. I-20131 Milano

6. Istituto di Chimica del Riconoscimento Molecolare – CNR

7. Italy

Abstract

The conversion of C₅ and C₆ cycloalkenecarboxylates into both enantiomers of the corresponding cyclic γ-oxoesters is performed at room temperature using three enzymes and no environmentally-unfriendly oxidants.

Funder

Fondazione Cariplo

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/GC/C7GC02215H

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