Synthesis, characterization, and catalytic application in aldehyde hydrosilylation of half-sandwich nickel complexes bearing (κ1-C)- and hemilabile (κ2-C,S)-thioether-functionalised NHC ligands

Author:

Ulm Franck12345,Poblador-Bahamonde Amalia I.6789,Choppin Sabine12345ORCID,Bellemin-Laponnaz Stéphane10311112ORCID,Chetcuti Michael J.12345,Achard Thierry10311112ORCID,Ritleng Vincent12345ORCID

Affiliation:

1. Université de Strasbourg

2. Université de Haute-Alsace

3. CNRS

4. LIMA

5. UMR 7042

6. Department of Organic Chemistry

7. University of Geneva

8. 1211 Geneva

9. Switzerland

10. Institut de Physique et Chimie des Matériaux de Strasbourg

11. UMR 7504

12. 67000 Strasbourg

Abstract

Ni complexes bearing thioether-functionalised NHCs; hemilabile ligands for catalytic aldehyde hydrosilylation.

Funder

Université de Strasbourg

Centre National de la Recherche Scientifique

Institut Universitaire de France

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference115 articles.

1. J. Louie , Ni-NHC mediated catalysis , in N-Heterocyclic Carbenes in Synthesis , ed. S. P. Nolan , Wiley-VCH , Weinheim , 2006 , pp. 163–182

2. Y. Fort and C.Comoy , NHC-Nickel and Platinum complexes , in N-Heterocyclic Carbenes: From Laboratory Curiosities to Efficient Synthetic Tools , ed. S. Díez-González , RSC Publishing , Cambridge , 2011 , pp. 284–326

3. M. T. Haynes II , E. P.Jackson and J.Montgomery , Nickel Complexes of N-Heterocyclic Carbenes , in N-Heterocyclic Carbenes: Effective Tools for Organometallic Synthesis , ed. S. P. Nolan , Wiley-VCH , Weinheim , 1st edn, 2014 , pp. 371–396

4. Nickel N-Heterocyclic Carbene-Catalyzed C–C Bond Formation: Reactions and Mechanistic Aspects

5. Nickel N-heterocyclic carbene complexes and their utility in homogeneous catalysis

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