Chemistry and structure by design: ordered CuNi(CN)4 sheets with copper(ii) in a square-planar environment-Reference-Cited by-同舟云学术

Chemistry and structure by design: ordered CuNi(CN)4 sheets with copper(ii) in a square-planar environment

Published:2015 Issue:28 Volume:44 Page:12502-12506
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Chippindale A. M.¹²³⁴,Hibble S. J.¹²³⁴,Marelli E.¹²³⁴,Bilbe E. J.¹²³⁴,Hannon A. C.⁵⁶⁷⁴,Zbiri M.⁸⁹¹⁰

Affiliation:

1. Department of Chemistry

2. University of Reading

3. Reading RG6 6AD

4. UK

5. ISIS Facility

6. Rutherford Appleton Laboratory

7. Didcot

8. Institut Laue-Langevin

9. F-38042 Grenoble Cedex 9

10. France

Abstract

Cu(ii) has been stabilised with square-planar coordination in a cyanide-only environment in the layered semiconducting material, copper–nickel cyanide, CuNi(CN)₄, which shows 2-D negative thermal expansion.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT01127B

Reference17 articles.

1. A. G. Sharpe , in ‘The Chemistry of Cyano Complexes of the Transition Metals’, Academic Press Inc., London, 1976

2. C. E. Housecroft and A. G.Sharpe, Inorganic Chemistry, Pearson Education Ltd, UK, 4th edn, 2012, p. 768

3. Surprises from a Simple Material—The Structure and Properties of Nickel Cyanide

4. Aperiodicity, structure, and dynamics inNi(CN)2

5. Relationship between phonons and thermal expansion in Zn(CN)2and Ni(CN)2from inelastic neutron scattering andab initiocalculations

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