The physical significance of the Kamlet–Taft π* parameter of ionic liquids

Author:

Weiß Nadine123ORCID,Schmidt Caroline H.123ORCID,Thielemann Gabi123ORCID,Heid Esther45678ORCID,Schröder Christian45678ORCID,Spange Stefan123ORCID

Affiliation:

1. Chemnitz University of Technology

2. 09111 Chemnitz

3. Germany

4. University of Vienna

5. Faculty of Chemistry

6. Institute for Computational Biological Chemistry

7. A-1090 Vienna

8. Austria

Abstract

The Kamlet–Taft dipolarity/polarizability parameters π* for various ionic liquids were determined using 4-tert-butyl-2-((dicyanomethylene)-5-[4-N,N-diethylamino)-benzylidene]-Δ3-thiazoline and 5-(N,N-dimethylamino)-5′-nitro-2,2′-bithiophene as solvatochromic probes.

Funder

Österreichischen Akademie der Wissenschaften

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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