Grafting transition metal–organophosphonate fragments onto heteropolyoxomolybdate: activity in photocatalysis
Author:
Affiliation:
1. Henan Key Laboratory of Polyoxometalate Chemistry
2. Institute of Molecular and Crystal Engineering
3. College of Chemistry and Chemical Engineering
4. Henan University
5. Kaifeng 475004
Abstract
Polyanion 1a can be seen as the structure decorated by three isolated {Ni(OOCCH2NHCH2PO3)2} based on the “Z-shaped” framework {Ni3O2(H2O)6(PMo6O24)2(μ3-O)2(μ2-O)6}.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT02471D
Reference55 articles.
1. Template synthesis of {(MoV2O4)(O3PCH2PO3)}nclusters (n = 3, 4, 10): solid state and solution studies
2. Two new cantilever-type polyoxometalates constructed from {Mo2O4}2+fragments and diphosphonates
3. Two diphosphonate-functionalized asymmetric polyoxomolybdates with catalytic activity for oxidation of benzyl alcohol to benzaldehyde
4. Novel Mixed-Valence Heteropolyoxometalates: A Molybdenum Diphosphonate Anion [MoV7MoVIO16(O3PPhPO3H)4]3- and Its One- and Two-Dimensional Assemblies
5. Tetra- to Dodecanuclear Oxomolybdate Complexes with Functionalized Bisphosphonate Ligands: Activity in Killing Tumor Cells
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