The S∴π hemibond and its competition with the S∴S hemibond in the simplest model system: infrared spectroscopy of the [benzene-(H2S)n]+ (n = 1–4) radical cation clusters-Reference-Cited by-同舟云学术

The S∴π hemibond and its competition with the S∴S hemibond in the simplest model system: infrared spectroscopy of the [benzene-(H2S)n]+ (n = 1–4) radical cation clusters

Published:2019 Issue:30 Volume:10 Page:7260-7268
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Wang Dandan¹²³⁴⁵,Hattori Keigo¹²³⁴⁵,Fujii Asuka¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Graduate School of Science

3. Tohoku University

4. Sendai 980-8578

5. Japan

Abstract

IR spectroscopy of [benzene-(H₂S)_n]⁺ (n = 1–4) elucidates the change of the positive charge accommodation motif from the S∴π hemibond to the S∴S hemibond.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/SC/C9SC02476J

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