Towards the rational design of ylide-substituted phosphines for gold(i)-catalysis: from inactive to ppm-level catalysis-Reference-Cited by-同舟云学术

Towards the rational design of ylide-substituted phosphines for gold(i)-catalysis: from inactive to ppm-level catalysis

Published:2021 Issue:12 Volume:12 Page:4329-4337
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Handelmann Jens¹²³⁴⁵,Babu Chatla Naga¹²³⁴⁵,Steinert Henning¹²³⁴⁵^ORCID,Schwarz Christopher¹²³⁴⁵,Scherpf Thorsten¹²³⁴⁵,Kroll Alexander¹²³⁴⁵,Gessner Viktoria H.¹²³⁴⁵^ORCID

Affiliation:

1. Faculty of Chemistry and Biochemistry

2. Chair of Inorganic Chemistry II

3. Ruhr University Bochum

4. 44801 Bochum

5. Germany

Abstract

Modification of the backbone in ylide-substituted phosphines allowed a remarkable boost in the catalytic activity, thus enabling a series of gold catalyzed transformations at very low catalyst loadings.

Funder

H2020 European Research Council

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC00105A

Reference69 articles.

1. Recent Applications of Palladium-Catalyzed Coupling Reactions in the Pharmaceutical, Agrochemical, and Fine Chemical Industries

2. Palladium-Catalyzed CN and CO Coupling-A Practical Guide from an Industrial Vantage Point†