Tandem dihetero-Diels–Alder and Huisgen cycloaddition reactions. Synthesis, crystal structure and hydrolysis of the novel cage phosphoranes
Author:
Affiliation:
1. Arbuzov Institute of Organic and Physical Chemistry
2. FRC Kazan Scientific Center of Russian Academy of Sciences
3. 420088 Kazan
4. Russian Federation
5. Institute of Physics
6. Kazan Federal University
7. 420008 Kazan
Abstract
The reaction of 2-(1-phenylvinyloxy)benzo-1,3,2-dioxaphosphole with activated carbonyl compounds leads to the stereoselective formation of cage phosphoranes.
Funder
Russian Foundation for Basic Research
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/QO/C8QO00915E
Reference79 articles.
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4. Atomic details of near-transition state conformers for enzyme phosphoryl transfer revealed by Formula rather than by phosphoranes
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