Crystal size versus paddle wheel deformability: selective gated adsorption transitions of the switchable metal–organic frameworks DUT-8(Co) and DUT-8(Ni)

Author:

Ehrling Sebastian1234ORCID,Senkovska Irena1234ORCID,Bon Volodymyr1234ORCID,Evans Jack D.1234ORCID,Petkov Petko5678ORCID,Krupskaya Yulia91034,Kataev Vladislav91034ORCID,Wulf Toshiki111213144ORCID,Krylov Alexander15161718ORCID,Vtyurin Alexander1516171819ORCID,Krylova Svetlana15161718ORCID,Adichtchev Sergey202118,Slyusareva Evgenia192218ORCID,Weiss Manfred S.2324254ORCID,Büchner Bernd91034ORCID,Heine Thomas262728294ORCID,Kaskel Stefan1234ORCID

Affiliation:

1. Chair of Inorganic Chemistry

2. Technische Universität Dresden

3. 01069 Dresden

4. Germany

5. University of Sofia

6. Faculty of Chemistry and Pharmacy

7. Sofia

8. Bulgaria

9. Leibniz Institute for Solid State and Materials Research

10. IFW Dresden

11. Wilhelm-Ostwald-Institute of Physical and Theoretical Chemistry

12. Faculty for Chemistry and Mineralogy

13. Leipzig University

14. 04103 Leipzig

15. Kirensky Institute of Physics

16. Federal Research Center KSC SB RAS

17. 660036 Krasnoyarsk

18. Russia

19. Siberian Federal University

20. Institute of Automation and Electrometry of the SB RAS

21. Novosibirsk

22. 660041 Krasnoyarsk

23. Research Group Macromolecular Crystallography

24. Helmholtz-Zentrum Berlin für Materialien und Energie

25. 12489 Berlin

26. Helmholtz-Zentrum Dresden-Rossendorf

27. Institute of Resource Ecology

28. Research Site Leipzig

29. 04318 Leipzig

Abstract

DUT-8(Co) shows a selective structural transition for CH2Cl2vs. CHCl3 and CCl4 at 298 K.

Funder

Deutsche Forschungsgemeinschaft

Helmholtz-Zentrum Berlin für Materialien und Energie

European Social Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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