Novel uranyl(vi) complexes incorporating propylene-bridged salen-type N2O2-ligands: a structural and computational approach-Reference-Cited by-同舟云学术

Novel uranyl(vi) complexes incorporating propylene-bridged salen-type N2O2-ligands: a structural and computational approach

Published:2015 Issue:2 Volume:44 Page:568-577
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Azam Mohammad¹²³⁴,Al-Resayes Saud I.¹²³⁴,Velmurugan Gunasekaran⁵⁶⁷⁸⁹,Venuvanalingam Ponnambalam⁵⁶⁷⁸⁹,Wagler Jörg¹⁰¹¹¹²¹³,Kroke Edwin¹⁰¹¹¹²¹³

Affiliation:

1. Department of Chemistry

2. King Saud University

3. Riyadh 11451

4. Kingdom of Saudi Arabia

5. Theoretical and Computational Chemistry Laboratory

6. School of Chemistry

7. Bharathidasan University

8. Tiruchirappalli – 620024

9. India

10. Institut für Anorganische Chemie

11. TU Bergakademie Freiberg

12. D-09596 Freiberg

13. Germany

Abstract

Synthesis of uranyl complex, [UO₂L(CH₃OH)] showing distorted pentagonal bipyramidal geometry and derived from a tetradentate dianionic ligand is reported. The computational study of the reported complex shows that its LUMO is featured with uranium f orbital character.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT02112F

Reference102 articles.

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2. Coordination of N-Donor Ligands to a Uranyl(V) β-Diketiminate Complex

3. Structural Characterization and Reactivity of UO2(salophen)L and [UO2(salophen)]2: Dimerization of UO2(salophen) Fragments in Noncoordinating Solvents (salophen = N,N‘-Disalicylidene-o-phenylenediaminate, L = N,N-Dimethylformamide, Dimethyl Sulfoxide)

4. Extended Structures and Physicochemical Properties of Uranyl–Organic Compounds

5. Hexaalkyl Terpyrrole: A New Building Block for the Preparation of Expanded Porphyrins

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