Stereoisomer-dependent unimolecular kinetics of 2,4-<b>dimethyloxetanyl</b> peroxy radicals-Reference-Cited by-同舟云学术

Stereoisomer-dependent unimolecular kinetics of 2,4-dimethyloxetanyl peroxy radicals

Published:2022 Issue: Volume:238 Page:295-319
ISSN:1359-6640
Container-title:Faraday Discussions
language:en
Short-container-title:Faraday Discuss.

Author:

Doner Anna C.¹^ORCID,Zádor Judit²^ORCID,Rotavera Brandon¹³^ORCID

Affiliation:

1. College of Engineering, Department of Chemistry, University of Georgia, Athens, Georgia 30602, USA

2. Combustion Research Facility, Sandia National Laboratories, 7011 East Avenue, Livermore, CA 94550, USA

3. Department of Chemistry, University of Georgia, Athens, Georgia 30602, USA

Abstract

The unimolecular decomposition of 2,4-dimethyloxetane peroxy radicals is a competition between conventional and ring opening pathways controlled by stereochemistry.

Funder

Basic Energy Sciences

National Science Foundation

Workforce Development for Teachers and Scientists

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/FD/D2FD00029F

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5. Infrared spectroscopic signature of a hydroperoxyalkyl radical (•QOOH)

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