Cobalt(iii)-containing penta-dentate “helmet”-type phthalogens: synthesis, solid-state structures and their thermal and electrochemical characterization

Author:

Al-Shewiki Rasha K.1,Weheabby Saddam2,Uhlig Nell1,Korb Marcus3ORCID,Pester Tom4,Zahn Stefan5,Grecchi S.6,Mussini P. R.6ORCID,Rüffer Tobias1ORCID,Lang Heinrich7ORCID

Affiliation:

1. Chemnitz University of Technology, Department of Inorganic Chemistry, Strasse der Nationen 62, 09107, Chemnitz, Germany

2. Chemnitz University of Technology, Measurement and Sensor Technology, 09126 Chemnitz, Germany

3. University of Western Australia, School of Molecular Sciences, M310, 6009 Perth, WA, Australia

4. Chemnitz University of Technology, Department of Organic Chemistry, Strasse der Nationen 62, 09111, Chemnitz, Germany

5. Leibniz Institute of Surface Engineering (IOM), Permoserstraße 15, 04318 Leipzig, Germany

6. University of Milan, Department of Chemistry, Via Golgi 19, 20133 Milano, Italy

7. Research Center for Materials, Architectures and Integration of Nano-membranes (MAIN) Research Group Organometallic Chemistry, Technische Universität Chemnitz Rosenbergstraße 6, 09126 Chemnitz, Germany

Abstract

Bulk quantities of “helmet” type phthalogens are now achievable with broad variation of their substituents allowing to study their thermal and electrochemical decomposition to CoPcs.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Reference116 articles.

1. B. D.Berezin , Coordination Compounds of Porphyrins and Phthalocyanines , Wiley , Chichester , 1981

2. N. B.McKeown , Phthalocyanine materials: Synthesis, Structure and Function , Cambridge University Press , 1998

3. C. C.Leznoff and A. B. P.Lever , Phthalocyanines: Properties and Applications , Wiley-VCH , New York , 1989 , 1993, 1993, 1996

4. The porphyrin handbook , ed. K. M. Kadish , K. M. Smith and R. Guilard , Academic , San Diego , 2003

5. M. S.Rodriguez-Morgade , G.de la Torre and T.Torres , in The Porphyrin Handbook , Academic Press , New York , 2003 , pp. 125–160

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