Mixed anhydride complexes of rhodium(i) and ruthenium(ii) – their synthesis and ligand rearrangements-Reference-Cited by-同舟云学术

Mixed anhydride complexes of rhodium(i) and ruthenium(ii) – their synthesis and ligand rearrangements

Published:2014 Issue:9 Volume:43 Page:3479-3491
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Coetzee Jacorien¹²³⁴⁵,Eastham Graham R.⁶⁷,Slawin Alexandra M. Z.¹²³⁴⁵,Cole-Hamilton David J.¹²³⁴⁵

Affiliation:

1. EaStCHEM

2. School of Chemistry

3. Purdie Building

4. University of St. Andrews

5. St. Andrews, UK

6. Lucite International Technology Centre

7. Middlesborough, UK

Abstract

The coordination chemistry and solution behaviour of Rh(i) and Ru(ii) complexes derived from mixed anhydride ligands were explored. Mixed anhydride complexes rearrange in solution via a number of pathways and plausible mechanisms for some of the rearrangements are proposed.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C3DT52552J

Reference38 articles.

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5. Notes. Upon the fluxionality of [RhCl(PPh3)(Ph2PO2CCHCHMe)]

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