Selective C–N coupling reaction of diaryliodonium salts and dinucleophiles
Author:
Affiliation:
1. State Key Laboratory of Geohazard Prevention and Geoenvironment Protection
2. Chengdu University of Technology
3. College of Materials
4. Chemistry & Chemical Engineering
5. 1#
6. College of Earth Science
7. Dongsanlu
8. Erxianqiao
Abstract
Ligand-free copper-catalyzed selective N-arylation of dinucleophiles including chiral α-amino amides with diaryliodonium salts as aryl electrophile equivalents was realized. Diaryliodonium salts prefer to react with dinucleophiles at the site of stronger basic amino groups.
Funder
Department of Science and Technology of Sichuan Province
National Natural Science Foundation of China
Education Department of Sichuan Province
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2017/NJ/C6NJ03964B
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