Dimethylnonacethrene – <i>en route</i> to a magnetic switch-Reference-Cited by-同舟云学术

Dimethylnonacethrene – en route to a magnetic switch

Published:2023 Issue:50 Volume:59 Page:7743-7746
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Čavlović Daniel¹^ORCID,Blacque Olivier¹^ORCID,Krummenacher Ivo²,Braunschweig Holger²^ORCID,Ravat Prince³⁴^ORCID,Juríček Michal¹⁴^ORCID

Affiliation:

1. Department of Chemistry, University of Zurich, Winterthurerstrasse 190, Zurich 8057, Switzerland

2. Institute of Inorganic Chemistry, Julius Maximilian University of Würzburg, Am Hubland, Würzburg 97074, Germany

3. Institute of Organic Chemistry, Julius Maximilian University of Würzburg, Am Hubland, Würzburg 97074, Germany

4. Department of Chemistry, University of Basel, St. Johanns-Ring 19, Basel 4056, Switzerland

Abstract

We report the first isolable cethrene derivative—dimethylnonacethrene. In contrast to all other reported cethrenes, this derivative is lower in energy compared to its electrocyclised product and has the lowest singlet–triplet gap in the series.

Funder

H2020 European Research Council

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Julius-Maximilians-Universität Würzburg

Universität Basel

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC01301D

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