Two new members of the niobium-substituted polytungstophosphate family based on hexalacunary [H2P2W12O48]12− building blocks-Reference-Cited by-同舟云学术

Two new members of the niobium-substituted polytungstophosphate family based on hexalacunary [H2P2W12O48]12− building blocks

Published:2015 Issue:3 Volume:2 Page:254-262
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Zhang Dongdi¹²³⁴⁵,Zhang Chao⁶³⁷⁸⁹,Ma Pengtao¹²³⁴⁵,Bassil Bassem S.¹⁰¹¹¹²¹³¹⁴,Al-Oweini Rami¹⁰¹¹¹²¹³¹⁴,Kortz Ulrich¹⁰¹¹¹²¹³,Wang Jingping¹²³⁴⁵,Niu Jingyang¹²³⁴⁵

Affiliation:

1. Key Laboratory of Polyoxometalate Chemistry of Henan Province

2. Institute of Molecular and Crystal Engineering

3. College of Chemistry and Chemical Engineering

4. Henan University

5. Kaifeng 475004

6. Collaborative Innovation Center of Chemistry for Energy Materials

7. Xiamen University

8. Xiamen 361005

9. P. R. China

10. School of Engineering and Science

11. Jacobs University

12. 28725 Bremen

13. Germany

14. Department of Chemistry

Abstract

Herein we present two structurally novel nanoscale clusters [{Nb₆(O₂)₄P₂W₁₂O₅₇}₂]²⁰⁻ (1) and [{P₂W₁₂Nb₇O₆₃(H₂O)₂}₄{Nb₄O₄(OH)₆}]³⁰⁻ (2) formed by controlling the reaction parameters.