Influence of molecular weight on molecular dynamics and dynamic rheology of polypropylene glycol filled with silica
Author:
Affiliation:
1. MOE Key Laboratory of Macromolecular Synthesis and Functionalization
2. Department of Polymer Science and Engineering
3. Zhejiang University
4. Hangzhou 310027
5. China
Abstract
The mobile phase exhibits an abnormal “more fragile” to “stronger” transition with increasing molecular weight of polypropylene glycol in nanocomposites at high silica loadings, which significantly lowers the degrees of reinforcement and thinning.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/RA/C8RA04497J
Reference94 articles.
1. Silicate Dispersion and Mechanical Reinforcement in Polysiloxane/Layered Silicate Nanocomposites
2. The role of interfacial interactions on the glass-transition and viscoelastic properties of silica/polystyrene nanocomposite
3. Polymer–filler interaction of fumed silica filled polydimethylsiloxane investigated by bound rubber
4. Interfacial Interactions and Segmental Dynamics of Poly(vinyl acetate)/Silica Nanocomposites
5. Rheology and Microstructure of Polymer Nanocomposite Melts: Variation of Polymer Segment−Surface Interaction
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