Difference in reaction mechanism between ZnZrOx and InZrOx for CO2 hydrogenation-Reference-Cited by-同舟云学术

Difference in reaction mechanism between ZnZrO_x and InZrO_x for CO₂ hydrogenation

Published:2024 Issue:18 Volume:26 Page:14037-14045
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Tada Shohei¹^ORCID,Ogura Yurika²,Sato Motohiro³,Yoshida Akihiro³⁴,Honma Tetsuo⁵^ORCID,Nishijima Masahiko⁶,Joutsuka Tatsuya⁷^ORCID,Kikuchi Ryuji¹^ORCID

Affiliation:

1. Division of Applied Chemistry, Graduate School of Engineering, Hokkaido University, Sapporo, Hokkaido 060-8628, Japan

2. Department of Materials Science and Engineering, Ibaraki University, 4-12-1, Nakanarusawa, Hitachi, Ibaraki 316-8511, Japan

3. Graduate School of Science and Technology, Hirosaki University, 3 Bunkyo-cho, Hirosaki, Aomori 030-8651, Japan

4. Institute of Regional Innovation, Hirosaki University, 3 Bunkyo-cho, Hirosaki, Aomori 030-8651, Japan

5. Japan Synchrotron Radiation Research Institute, Sayo-gun, Hyogo 679-5198, Japan

6. Flexible 3D System Integration Laboratory, Osaka University, 8-1 Mihogaoka Ibaraki-Shi, Osaka 567-0047, Japan

7. Department of Materials Science and Engineering, Ehime University, 3 Bunkyo-cho, Matsuyama, Ehime 790-8577, Japan

Abstract

For ZnZrOx, methoxy group decomposition is partially suppressed due to its relatively high stability, whereas InZrOx promotes methoxy species conversion to methyl groups through strong adsorption of the methyl group on In3+.

Funder

Environmental Restoration and Conservation Agency

Japan Society for the Promotion of Science

New Energy and Industrial Technology Development Organization

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CP/D4CP00635F

Reference40 articles.

1. The Active Site of Methanol Synthesis over Cu/ZnO/Al 2 O 3 Industrial Catalysts

2. Quantifying the promotion of Cu catalysts by ZnO for methanol synthesis

3. Active sites for CO 2 hydrogenation to methanol on Cu/ZnO catalysts

4. Methanol-to-hydrocarbons: catalytic materials and their behavior

5. Challenges in the Greener Production of Formates/Formic Acid, Methanol, and DME by Heterogeneously Catalyzed CO2 Hydrogenation Processes

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