Base-switched annuloselectivity in the reactions of ethyl malonyl chloride and imines-Reference-Cited by-同舟云学术

Base-switched annuloselectivity in the reactions of ethyl malonyl chloride and imines

Published:2014 Issue:48 Volume:12 Page:9822-9830
ISSN:1477-0520
Container-title:Org. Biomol. Chem.
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Yang Zhanhui¹²³⁴⁵,Li Siqi¹²³⁴⁵,Zhang Zhong¹²³⁴⁵,Xu Jiaxi¹²³⁴⁵

Affiliation:

1. State Key Laboratory of Chemical Resource Engineering

2. Department of Organic Chemistry

3. Faculty of Science

4. Beijing University of Chemical Technology

5. Beijing 100029, P. R. China

Abstract

The [2 + 2] and [2 + 2 + 2] annuloselectivity in the reactions of ethyl malonyl chloride with imines was controlled by different bases, providing a simple synthesis of β-lactam-3-carboxylates and 2,3-dihydro-1,3-oxazin-4-ones.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/OB/C4OB01454E

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