A new skeletal rearrangement of 1,7-dimethyl Cookson's cage dione catalyzed by a Lewis acid-Reference-Cited by-同舟云学术

A new skeletal rearrangement of 1,7-dimethyl Cookson's cage dione catalyzed by a Lewis acid

Published:2020 Issue:7 Volume:18 Page:1377-1383
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Kotha Sambasivarao¹²³⁴^ORCID,Cheekatla Subba Rao¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology-Bombay

3. Powai

4. India

Abstract

An unexpected fragmentation of the pentacycloundecane (PCUD) framework delivers two unusual polycycles in an unprecedented approach via an extensive C–C bond reorganization promoted by the BF₃·MeOH complex.

Funder

Defence Research and Development Organisation

Department of Science and Technology, Ministry of Science and Technology, India

University Grants Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/OB/C9OB02298H

Reference80 articles.

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4. Synthesis and chemistry of homocubanes, bishomocubanes, and trishomocubanes

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