The keto–enol tautomerization of ethyl acetoacetate in choline ionic liquids: the role of cation and anion in switching the tautomeric equilibrium-Reference-Cited by-同舟云学术

The keto–enol tautomerization of ethyl acetoacetate in choline ionic liquids: the role of cation and anion in switching the tautomeric equilibrium

Published:2021 Issue:12 Volume:23 Page:7386-7397
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Kumar Madhu Deepan¹²³⁴⁵,Jaccob Madhavan¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry & Computational Chemistry Laboratory

2. Loyola Institute of Frontier Energy (LIFE)

3. Loyola College

4. University of Madras

5. Chennai 600 034

Abstract

In the present study, the specific role of the individual cations and anions of ionic liquids in shifting the tautomeric equilibrium of EAA was investigated.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D0CP05090C

Reference38 articles.

1. Benchmarking Continuum Solvent Models for Keto–Enol Tautomerizations

2. Gas-phase proton NMR studies of keto-enol tautomerism of acetylacetone, methyl acetoacetate, and ethyl acetoacetate

3. Cholinium ionic liquids as cheap and reusable catalysts for the synthesis of coumarins via Pechmann reaction under solvent-free conditions

4. Use of Ionic Liquid To Significantly Improve Asymmetric Reduction of Ethyl Acetoacetate Catalyzed by Acetobacter sp. CCTCC M209061 Cells

5. Combined Role of the Asymmetric Counteranion-Directed Catalysis (ACDC) and Ionic Liquid Effect for the Enantioselective Biginelli Multicomponent Reaction

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