Intramolecular CH3-migration-controlled cation reactions in the VUV photochemistry of 2-methyl-3-buten-2-ol investigated by synchrotron photoionization mass spectrometry and theoretical calculations
Author:
Affiliation:
1. National Synchrotron Radiation Laboratory
2. University of Science and Technology of China
3. Hefei
4. P. R. China
Abstract
CH3 migration-controlled fragmentations via conventional TS and roaming pathways are reported in the dissociative photoionization of 2-methyl-3-buten-2-ol, which are examined by synchrotron photoionization spectroscopy and theoretical calculations.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2021/CP/D1CP00490E
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