Regulating the microscopic structure of solutions to synthesize centimeter-sized low-dimensional CsmSbnClm+3n perovskite single crystals for visible-blind ultraviolet photodetectors

Author:

Wang Wenzhen123ORCID,Xu Shanhu1,Lai Ziyi1,Feng Xiaoxi1,Qi Huanzhen1,Pan Qiutao1,Yang Zichen4,Kang Jiaxing4,Li Yue4,Shu Xin4,Zhang Zifa4,Zhu Yan3,Bai Jiaxin5,Hong Feng4ORCID,Qin Juan2,Xu Run12ORCID,He Ying4,Xu Fei4,Wang Linjun124

Affiliation:

1. School of Materials Science and Engineering, Shanghai University, 333 Nanchen Road, Shanghai 200444, China

2. Zhejiang Institute of Advanced Materials, SHU, 1588 Huaxiang Street, Jiashan 314113, China

3. Shanghai Technical Institute of Electronics & Information, 3098 Wahong Road, Shanghai 201411, China

4. Department of Physics, College of Sciences, Shanghai University, 99 Shangda Road, Shanghai 200444, China

5. Hebei Institute of Pure Iron Materials and Application Industry Technology, Handan 056300, China

Abstract

Centimeter-sized CsmSbnClm+3n single crystals were prepared by using DMSO and hydrochloric acid. The α-Cs3Sb2Cl9 photodetector exhibits excellent wavelength selectivity and fast response speed, demonstrating its great potential in UV applications.

Funder

National Natural Science Foundation of China

Postdoctoral Research Foundation of China

Hebei Provincial Key Research Projects

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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